Sebastian Stan started to really enter the public eye with his recurring role on Gossip Girl from 2007 to 2010, but it was just after that time when he became a global star thanks to his role as Bucky Barnes in 2011’s Captain America: The First Avenger. Considering he’s still playing the role (including in 2025’s Thunderbolts*), he’s had one of the longest tenures of any MCU star.
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